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This article presents rigorous mathematical analysis of the Redfield equation within open quantum systems, specifically addressing the preservation of complete positivity through various resummation techniques like Magnus and resolvent methods. By establishing a weak-coupling criterion for non-Markovian dynamics, the work clarifies the reliability limits of standard perturbative approaches in quantum simulations. These findings are critical for advancing accurate modeling of decoherence and thermalization in quantum hardware and algorithms.
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How I Learned to Stop Worrying and Love the Redfield Equation: Completely-Positive Resummation of Non-Markovian Dynamics

arXiv2 min read

arXiv:2610.03676v1 Announce Type: new Abstract: The Redfield equation with time-dependent coefficients (or TCL2 equation) gives one of the simplest perturbative descriptions of open quantum system dynamics derived from a microscopic theory. Its status as an approximation is nevertheless subtle: while perturbation theory fixes the reduced dynamics order-by-order in the system-environment coupling, solving the Redfield equation yields a particular resummation that need not preserve complete positivity. Here we compare Redfield evolution with an exponentiated (Magnus) resummation of the same second-order perturbative map, which is completely positive and trace preserving (CPTP) for a broad class of physical conditions. We also construct a simple CPTP resolvent resummation, illustrating the non-uniqueness of resummations of the same perturbative map. The Redfield and Magnus prescriptions agree to second order but differ through time-ordering corrections at higher orders. We exhibit a weak-coupling criterion which guarantees that Redfield evolution, even when non-Markovian, remains close to a CPTP map. We illustrate the criterion in two examples, focusing on finite-dimensional (qubit) systems. Our results clarify when, and why, Redfield evolution can remain reliable even when it is highly non-Lindbladian.

Abstract:The Redfield equation with time-dependent coefficients (or TCL2 equation) gives one of the simplest perturbative descriptions of open quantum system dynamics derived from a microscopic theory. Its status as an approximation is nevertheless subtle: while perturbation theory fixes the reduced dynamics order-by-order in the system-environment coupling, solving the Redfield equation yields a particular resummation that need not preserve complete positivity. Here we compare Redfield evolution with an exponentiated (Magnus) resummation of the same second-order perturbative map, which is completely positive and trace preserving (CPTP) for a broad class of physical conditions. We also construct a simple CPTP resolvent resummation, illustrating the non-uniqueness of resummations of the same perturbative map. The Redfield and Magnus prescriptions agree to second order but differ through time-ordering corrections at higher orders. We exhibit a weak-coupling criterion which guarantees that Redfield evolution, even when non-Markovian, remains close to a CPTP map. We illustrate the criterion in two examples, focusing on finite-dimensional (qubit) systems. Our results clarify when, and why, Redfield evolution can remain reliable even when it is highly non-Lindbladian.

arXiv:2610.03676 [quant-ph]

(or arXiv:2610.03676v1 [quant-ph] for this version)

https://doi.org/10.48550/arXiv.2610.03676 Focus to learn more arXiv-issued DOI via DataCite (pending registration)

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Full text under the publisher's open licence · 265 words

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