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This research investigates the thermodynamic limits of work extraction in quantum spin chains, specifically analyzing how integrability affects entropy production during non-adiabatic driving. The study reveals that breaking integrality can enhance energy efficiency under slow protocols but introduces frictional losses at faster speeds or low temperatures due to complex coherence dynamics. These findings provide critical theoretical bounds for optimizing control strategies in future quantum heat engines and information processing devices.
Frictional work and entropy production in integrable and non-integrable spin chains
arXiv:2601.15941v2 Announce Type: replace Abstract: The maximum work extractable from a quantum system is achieved when the system is driven adiabatically. Frictional work $\langle W\rangle_\mathrm{fric}$ then quantifies the difference in work output between adiabatic and non-adiabatic driving. Here we show that frictional work in a non-integrable spin chain is well-characterized by the diagonal entropy production $\Delta S_\mathrm{d}$ associated with the build up of quantum coherence. We show that, over a broad range of parameters, $\langle W\rangle_\mathrm{fric}\approx T_\tau\Delta S_\mathrm{d}$, with $T_\tau$ the effective temperature of the final time-evolved state. The relationship breaks down for fast protocols at low temperatures, in which case frictional work is instead well-described by the quantum relative entropy between the time-evolved state and a Gibbs-state approximation of the adiabatic state. We compare our results to those obtained from an integrable spin chain, in which case the system is no longer described by a single temperature. In this case, the frictional work is described by a sum of terms for each independent subspace of the spin chain, which are at different effective temperatures. Finally, we show how integrability breaking can enhance work extraction in the adiabatic limit, but degrade work extraction in sufficiently non-adiabatic regimes.
Abstract:The maximum work extractable from a quantum system is achieved when the system is driven adiabatically. Frictional work $\langle W\rangle_\mathrm{fric}$ then quantifies the difference in work output between adiabatic and non-adiabatic driving. Here we show that frictional work in a non-integrable spin chain is well-characterized by the diagonal entropy production $\Delta S_\mathrm{d}$ associated with the build up of quantum coherence. We show that, over a broad range of parameters, $\langle W\rangle_\mathrm{fric}\approx T_\tau\Delta S_\mathrm{d}$, with $T_\tau$ the effective temperature of the final time-evolved state. The relationship breaks down for fast protocols at low temperatures, in which case frictional work is instead well-described by the quantum relative entropy between the time-evolved state and a Gibbs-state approximation of the adiabatic state. We compare our results to those obtained from an integrable spin chain, in which case the system is no longer described by a single temperature. In this case, the frictional work is described by a sum of terms for each independent subspace of the spin chain, which are at different effective temperatures. Finally, we show how integrability breaking can enhance work extraction in the adiabatic limit, but degrade work extraction in sufficiently non-adiabatic regimes.
Quantum Physics (quant-ph); Statistical Mechanics (cond-mat.stat-mech)
arXiv:2601.15941 [quant-ph]
(or arXiv:2601.15941v2 [quant-ph] for this version)
https://doi.org/10.48550/arXiv.2601.15941 Focus to learn more arXiv-issued DOI via DataCite
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