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This research provides a high-precision measurement of the differential scalar polarizability in barium ions, offering critical validation for atomic structure calculations used in next-generation optical clocks. By refining models for blackbody radiation shifts and matrix elements, these findings directly enhance the stability and accuracy required for quantum metrology applications.
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Zero crossings of the differential scalar polarizability of Ba$^+$ clock transition

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arXiv:2603.10740v2 Announce Type: replace-cross Abstract: The differential scalar polarizability $\Delta\alpha_0(\omega)$ of the Ba$^+$ S$_{1/2}$-to-D$_{5/2}$ clock transition has a zero crossing near 481nm, which is measured to be 623.603\,13(17)\,THz. From this measurement, we infer a ratio of reduced matrix elements $\langle P_{3/2}\|r\|S_{1/2}\rangle/\langle P_{1/2}\|r\|S_{1/2}\rangle=1.411\,81(13)$, which provides a stringent test of atomic structure calculations and experimental determination of matrix elements. Additionally, it enables the construction of an accurate approximation to $\Delta\alpha_0(\omega)$, valid for frequencies up to 450\,THz, with only one reduced matrix element, $\langle P_{1/2}\|r\|S_{1/2}\rangle$, appearing in the model's parameterization. We discuss the achievable accuracy of the model, the application to the assessment of blackbody radiation (BBR) shifts in ion-based clocks, and the applicability of the approach to other alkaline-earth ions.

Abstract:The differential scalar polarizability $\Delta\alpha_0(\omega)$ of the Ba$^+$ S$_{1/2}$-to-D$_{5/2}$ clock transition has a zero crossing near 481nm, which is measured to be 623.603\,13(17)\,THz. From this measurement, we infer a ratio of reduced matrix elements $\langle P_{3/2}\|r\|S_{1/2}\rangle/\langle P_{1/2}\|r\|S_{1/2}\rangle=1.411\,81(13)$, which provides a stringent test of atomic structure calculations and experimental determination of matrix elements. Additionally, it enables the construction of an accurate approximation to $\Delta\alpha_0(\omega)$, valid for frequencies up to 450\,THz, with only one reduced matrix element, $\langle P_{1/2}\|r\|S_{1/2}\rangle$, appearing in the model's parameterization. We discuss the achievable accuracy of the model, the application to the assessment of blackbody radiation (BBR) shifts in ion-based clocks, and the applicability of the approach to other alkaline-earth ions.

Atomic Physics (physics.atom-ph); Quantum Physics (quant-ph)

arXiv:2603.10740 [physics.atom-ph]

(or arXiv:2603.10740v2 [physics.atom-ph] for this version)

https://doi.org/10.48550/arXiv.2603.10740 Focus to learn more arXiv-issued DOI via DataCite

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