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This research establishes rigorous criteria for when pseudomode models achieve thermodynamic consistency, specifically addressing the conditions under which open quantum systems properly thermalize to a Gibbs state without relying on perturbative approximations. By analyzing both Hermitian and non-Hermitian configurations, the study provides essential guidelines for constructing accurate simulations of strong system-bath interactions where standard intuition regarding weak coupling may fail. These findings are critical for advancing reliable modeling in quantum thermodynamics and open-system dynamics.
Thermalization of open quantum systems with pseudomodes
arXiv:2608.02517v1 Announce Type: new Abstract: Pseudomode approaches allow for an exact and unapproximated description of a quantum system interacting arbitrarily strongly with a bath. In general, a system coupled to pseudomodes will not thermalize to the system's Gibbs state: This is to be expected when the system-bath coupling is non-perturbative, but conflicts with common thermodynamic intuition when the system-bath coupling is asymptotically weak. We explore under which circumstances pseudomode models satisfy detailed balance (and subsequently thermalize to the system Gibbs state) and how specific choices of parameters can force "weak" detailed balance that is restricted to a limited frequency range. A combination of Hermitian and non-Hermitian pseudomodes that yields a flat effective-temperature profile is also considered. The results and criteria established here are relevant for the construction of pseudomode models in contexts where thermodynamic consistency is required.
Abstract:Pseudomode approaches allow for an exact and unapproximated description of a quantum system interacting arbitrarily strongly with a bath. In general, a system coupled to pseudomodes will not thermalize to the system's Gibbs state: This is to be expected when the system-bath coupling is non-perturbative, but conflicts with common thermodynamic intuition when the system-bath coupling is asymptotically weak. We explore under which circumstances pseudomode models satisfy detailed balance (and subsequently thermalize to the system Gibbs state) and how specific choices of parameters can force "weak" detailed balance that is restricted to a limited frequency range. A combination of Hermitian and non-Hermitian pseudomodes that yields a flat effective-temperature profile is also considered. The results and criteria established here are relevant for the construction of pseudomode models in contexts where thermodynamic consistency is required.
Quantum Physics (quant-ph); Statistical Mechanics (cond-mat.stat-mech); Chemical Physics (physics.chem-ph); Computational Physics (physics.comp-ph)
arXiv:2608.02517 [quant-ph]
(or arXiv:2608.02517v1 [quant-ph] for this version)
https://doi.org/10.48550/arXiv.2608.02517 Focus to learn more arXiv-issued DOI via DataCite (pending registration)
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