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This research demonstrates a fundamental limitation in the level-3 quantum bootstrap method for a specific three-dimensional Hamiltonian, proving that certain mathematically valid relaxations do not correspond to any physical quantum state. By constructing an interior point with a strictly positive definite moment matrix that fails the positivity test on nonnegative polynomials, the study provides rigorous algebraic certificates showing where current approximation bounds fall short of capturing true spectral properties. The work advances theoretical understanding of eigenstate constraints and highlights the gap between relaxed optimization problems and exact quantum mechanical solutions in higher dimensions.
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Strict non-tightness of the level-3 quantum bootstrap for a natural three-dimensional Hamiltonian, at an excited level

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arXiv:2610.03362v1 Announce Type: new Abstract: For the coupled three-dimensional double well $H=\tfrac12|p|^2+2\sum_i(q_i^2-1)^2-\sum_{i<j}q_i^2q_j^2$ we exhibit, at the first excited energy level (and also at the ground state), a linear functional on polynomials of degree $\le 6$ that satisfies every constraint of the standard level-3 eigenstate bootstrap, has a \emph{strictly} positive definite moment matrix, and nevertheless assigns a negative value to a nonnegative polynomial. It is therefore an interior point of the level-3 relaxation that is realized by no quantum state. The construction reflects a fact that holds at every level: the eigenstate rows never reach the top-degree momentum moments. At level 3, where strictly feasible points exist, this means that the corresponding block of the moment matrix carries no information about which energies admit one. Every algebraic ingredient is an exact rational certificate, and the only numerical ingredients (spectral enclosures of an eigenfunction) are carried out in rigorous ball arithmetic.

Abstract:For the coupled three-dimensional double well $H=\tfrac12|p|^2+2\sum_i(q_i^2-1)^2-\sum_{i<j}q_i^2q_j^2$ we exhibit, at the first excited energy level (and also at the ground state), a linear functional on polynomials of degree $\le 6$ that satisfies every constraint of the standard level-3 eigenstate bootstrap, has a \emph{strictly} positive definite moment matrix, and nevertheless assigns a negative value to a nonnegative polynomial. It is therefore an interior point of the level-3 relaxation that is realized by no quantum state. The construction reflects a fact that holds at every level: the eigenstate rows never reach the top-degree momentum moments. At level 3, where strictly feasible points exist, this means that the corresponding block of the moment matrix carries no information about which energies admit one. Every algebraic ingredient is an exact rational certificate, and the only numerical ingredients (spectral enclosures of an eigenfunction) are carried out in rigorous ball arithmetic.

14 pages. Code and certificates included as ancillary files

arXiv:2610.03362 [quant-ph]

(or arXiv:2610.03362v1 [quant-ph] for this version)

https://doi.org/10.48550/arXiv.2610.03362 Focus to learn more arXiv-issued DOI via DataCite (pending registration)

lemmaT3_A2_c5.txt

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