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This article addresses a critical challenge in AI applications for energy storage by integrating physical battery degradation laws into neural network training objectives. The proposed PiDDM framework demonstrates superior accuracy and long-term extrapolation stability compared to purely data-driven models, effectively preventing physically implausible predictions like capacity regeneration. This approach represents a significant advancement in physics-informed machine learning (PINN) specifically tailored for reliable state-of-health monitoring across diverse operating conditions.
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PiDDM: Physics-Informed Differentiable Degradation Modeling for Lithium-Ion Battery State-of-Health Prediction

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arXiv:2607.29095v1 Announce Type: new Abstract: Accurate prediction of lithium-ion battery state of health (SOH) is essential for reliable energy storage operation. However, purely data-driven models may generalize poorly across cycling protocols and produce physically implausible behavior during long-term extrapolation. We developed a physics-informed differentiable degradation modeling framework (PiDDM) for battery SOH prediction. PiDDM incorporates empirical Arrhenius degradation kinetics associated with solid electrolyte interphase growth and loss of lithium inventory into the training objective, encouraging physically consistent capacity fade under diverse operating conditions. The framework was evaluated using a public dataset of 55 batteries cycled under six operating protocols. PiDDM achieved the lowest average prediction error among the evaluated models and substantially reduced mean squared error relative to a multilayer perceptron and a baseline physics-informed neural network. For extrapolation, the models were trained on the first 90% of each battery's cycle life and evaluated on the unseen final 10%. PiDDM captured accelerated end-of-life degradation while avoiding the nonphysical capacity regeneration produced by the baseline models. These results show that incorporating degradation physics into neural network training improves predictive accuracy and physical consistency, providing a promising approach for practical battery health monitoring.

Abstract:Accurate prediction of lithium-ion battery state of health (SOH) is essential for reliable energy storage operation. However, purely data-driven models may generalize poorly across cycling protocols and produce physically implausible behavior during long-term extrapolation. We developed a physics-informed differentiable degradation modeling framework (PiDDM) for battery SOH prediction. PiDDM incorporates empirical Arrhenius degradation kinetics associated with solid electrolyte interphase growth and loss of lithium inventory into the training objective, encouraging physically consistent capacity fade under diverse operating conditions. The framework was evaluated using a public dataset of 55 batteries cycled under six operating protocols. PiDDM achieved the lowest average prediction error among the evaluated models and substantially reduced mean squared error relative to a multilayer perceptron and a baseline physics-informed neural network. For extrapolation, the models were trained on the first 90% of each battery's cycle life and evaluated on the unseen final 10%. PiDDM captured accelerated end-of-life degradation while avoiding the nonphysical capacity regeneration produced by the baseline models. These results show that incorporating degradation physics into neural network training improves predictive accuracy and physical consistency, providing a promising approach for practical battery health monitoring.

Machine Learning (cs.LG)

arXiv:2607.29095 [cs.LG]

(or arXiv:2607.29095v1 [cs.LG] for this version)

https://doi.org/10.48550/arXiv.2607.29095 Focus to learn more arXiv-issued DOI via DataCite (pending registration)

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