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This study presents an analytical advancement in quantum mechanics by utilizing a scaled Kratzer basis to achieve sub-1% accuracy for bound-state energies in screened Coulomb potentials. The methodology is particularly relevant for modeling atomic systems within plasma environments and condensed matter physics where screening effects significantly alter standard interactions. By refining variational optimization techniques, the work establishes new benchmarks for precision calculations involving hydrogen-like atoms and Positronium with arbitrary reduced mass.
LPRIM’s Kratzer Basis Improves Bound-State Accuracy to 1% at Screening

Using a Kratzer basis, researchers achieved 1% relative errors for the first ten s-states of hydrogen-like atoms in screened Coulomb potentials.
Researchers at LPRIM, University of Batna I, and collaborating institutions University of Biskra and University of Khenchela, have achieved relative errors of less than one percent in calculating the bound-state energies for the first ten s-states of hydrogen-like atoms using a novel analytical approach. The work, focused on atoms interacting with a radial screened Coulomb potential, combines expectation values, variational optimization with a scaled Kratzer basis, and the Hellmann-Feynman theorem to provide robust error estimation. This formalism not only refines calculations for systems embedded in plasma but also extends successfully to Positronium, demonstrating applicability to atoms with arbitrary reduced mass. The team benchmarked their results against high-precision data, establishing a new level of accuracy for these complex quantum systems. Approximate energy eigenvalues have been achieved in calculating the bound-state energies of…
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