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This research applies quantum entanglement and heralded detection techniques to improve the signal-to-noise ratio in fluorescence spectroscopy for organic light-emitting materials. By leveraging timing correlations between photon pairs, the method effectively suppresses background noise and reduces photobleaching issues common in conventional measurements. This advancement represents a practical application of quantum principles to enhance precision in optoelectronics and bioimaging research.
Development of time-resolved fluorescence spectroscopy using heralded emission spectroscopy for organic light-emitting materials
arXiv:2611.07770v1 Announce Type: new Abstract: Organic light-emitting materials are widely used in optoelectronics and bioimaging, but sometimes conventional fluorescence spectroscopy techniques can be limited by scattering, background fluorescence, photon pile-up and photobleaching. We report a quantum-spectroscopic approach using frequency-entangled, nondegenerate photon pairs generated via spontaneous parametric down-conversion with heralded detection, to perform photoluminescence lifetime measurements at low excitation intensities. We demonstrate this approach across three organic light-emitting material classes: the fluorescent dye Rhodamine 6G, an organic semiconducting conjugated polymer poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), and a fluorescent protein mOrange. The intrinsic timing correlation between signal and idler photons enables coincidence gating that suppresses uncorrelated background counts. Across all materials and integration times of 500, 1000 and 3600 seconds, heralded detection yields signal-to-noise ratios 1.6-3.0 times higher than classical pulsed-laser excitation attenuated to match heralded photon counts in the fitting range. For MEH-PPV, this roughly halves the noise amplitude. Our measured lifetimes closely match long-integration classical pulsed-laser reference values.
Abstract:Organic light-emitting materials are widely used in optoelectronics and bioimaging, but sometimes conventional fluorescence spectroscopy techniques can be limited by scattering, background fluorescence, photon pile-up and photobleaching. We report a quantum-spectroscopic approach using frequency-entangled, nondegenerate photon pairs generated via spontaneous parametric down-conversion with heralded detection, to perform photoluminescence lifetime measurements at low excitation intensities. We demonstrate this approach across three organic light-emitting material classes: the fluorescent dye Rhodamine 6G, an organic semiconducting conjugated polymer poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), and a fluorescent protein mOrange. The intrinsic timing correlation between signal and idler photons enables coincidence gating that suppresses uncorrelated background counts. Across all materials and integration times of 500, 1000 and 3600 seconds, heralded detection yields signal-to-noise ratios 1.6-3.0 times higher than classical pulsed-laser excitation attenuated to match heralded photon counts in the fitting range. For MEH-PPV, this roughly halves the noise amplitude. Our measured lifetimes closely match long-integration classical pulsed-laser reference values.
arXiv:2611.07770 [quant-ph]
(or arXiv:2611.07770v1 [quant-ph] for this version)
https://doi.org/10.48550/arXiv.2611.07770 Focus to learn more arXiv-issued DOI via DataCite (pending registration)
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