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This paper establishes a rigorous framework for entropy production in quantum systems by defining a Hermitian operator valid even when non-commutativity is present, thereby extending classical fluctuation theorems to fully quantum regimes. By utilizing Bayesian retrodiction and the Petz transpose map, it provides explicit expressions that clarify how thermodynamic expectations diverge from standard models at the quantum level. This theoretical advance offers foundational tools for analyzing irreversibility in open quantum systems without relying on commutative approximations.
A quantum entropy production operator
arXiv:2412.12489v4 Announce Type: replace Abstract: We introduce a fully quantum notion of entropy production based on the non-commutative extension of the classical log-ratio between forward and reverse processes. Given a pair of quantum objects associated with the forward and reverse descriptions, we define a Hermitian entropy-production operator whose expectation value is non-negative and equal to the Belavkin--Staszewski relative entropy. The operator satisfies exact integral and detailed fluctuation theorems without requiring commutativity. We then specialize this construction to the case in which the forward process is described by a single quantum channel and the reverse process is defined inferentially, through Bayesian retrodiction relative to a prior state, with the Petz transpose map as the Bayesian inverse. In this setting, the relevant quantities can be evaluated explicitly, leading to a number of natural structural and physical properties. The framework recovers the classical formula in the commutative limit, yields explicit expressions for the average entropy production, and clarifies where the fully quantum case departs from standard thermodynamic expectations.
Abstract:We introduce a fully quantum notion of entropy production based on the non-commutative extension of the classical log-ratio between forward and reverse processes. Given a pair of quantum objects associated with the forward and reverse descriptions, we define a Hermitian entropy-production operator whose expectation value is non-negative and equal to the Belavkin--Staszewski relative entropy. The operator satisfies exact integral and detailed fluctuation theorems without requiring commutativity. We then specialize this construction to the case in which the forward process is described by a single quantum channel and the reverse process is defined inferentially, through Bayesian retrodiction relative to a prior state, with the Petz transpose map as the Bayesian inverse. In this setting, the relevant quantities can be evaluated explicitly, leading to a number of natural structural and physical properties. The framework recovers the classical formula in the commutative limit, yields explicit expressions for the average entropy production, and clarifies where the fully quantum case departs from standard thermodynamic expectations.
arXiv:2412.12489 [quant-ph]
(or arXiv:2412.12489v4 [quant-ph] for this version)
https://doi.org/10.48550/arXiv.2412.12489 Focus to learn more arXiv-issued DOI via DataCite
Bai, Ge, Francesco Buscemi, and Valerio Scarani. "A quantum entropy production operator." Journal of Physics A: Mathematical and Theoretical (2024)
https://doi.org/10.1088/1751-8121/ae86cb Focus to learn more DOI(s) linking to related resources
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